1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Basic information

Reaction

Product Name:	(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)
Synonyms:	(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-di-phenylphoshinobenzoyl);(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl),98%(R,R)-DACH-PhenylTrostLigand;(R,R)-DACH-phenyl Trost ligand;(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), 98% (R,R)-DACH-Phenyl;(1R,2R)-(+)-N,N'-Bis(2-diphenylphosphinobenzoyl)-1,2-diaminocyclohexane;1R,2R- DHAC-Phenyl Trost Ligand;(1R,2R)-(+)-1,2-DiaMinocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), (R,R)-DACH-Phenyl Trost Ligand;(R,R)-DACH-phenyl Trost ligand 95%
CAS:	138517-61-0
MF:	C44H40N2O2P2
MW:	690.75
EINECS:
Product Categories:	Chiral Nitrogen;DACH&Trost Series
Mol File:	138517-61-0.mol

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Chemical Properties

Melting point	134-136°C
alpha	+130° (c 1.0, methanol)
form	Powder
color	white to off-white
optical activity	[α]20/D +131°, c = 1 in methanol

Safety Information

Risk Statements	36/37/38
Safety Statements	26-36/37/39
WGK Germany	3

MSDS Information

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Usage And Synthesis

Reaction

The palladium complexes of the Trost ligands are effective in a variety of allylic substitution reactions involving carbon, nitrogen, oxygen, sulfur, and fluorides nucleophiles.

 

 

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Our R&D team masters core technology for process-design of target building block as well as Tailor-made fine chemicals. Our manufactory specialised in extreme temperature conditions (-100ºC to +300ºC), hydrogenations reaction under high pressure, suzuki coupling reaction, photochemical reaction, Mitsunobu reactions, enantioselective reactions and asymmetric synthesis. 

 

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